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4. Plastic products:

household, agriculture, construction and traffic

4.1. Tell about the applications of polymers in the household, agriculture, construction and traffic Household: Non-stick pan--The bottom of the pan is coated with a layer of polytetrafluoroethylene so that cooking will not stick to the bottom of the pan. polytetrafluoroethylene has good chemical resistance, aging resistance, easy cleaning performance and no toxicity (Wang, 2018). Besides, many clothes, tableware and some food containers are also made of polymer materials, such as plastic fork and bottle, and clothes that is made of nylon.

Agriculture: Water pipes made of PVC are used for agricultural irrigation, and plastic film is used in agricultural greenhouses. Besides, vegetable and fruit packaging are also made of polymer materials to reduce the cost.

Construction: PE, PVC, PS, PP, PF are commonly used as the raw material of construction plastic. For example, PE is mostly used as a waterproof material, and PS is mainly used as thermal insulation material in the form of foam plastic.

Traffic: Rubber is widely used to make tires, which greatly improves the bumps caused by transportation. Polymer materials are also widely used in aerospace. For example, carbon fiber

composite materials can be used for aircraft main structures such as a frame and wings. Moreover, ship hulls and automobile shells could also be made of polymer materials.

4.2. Tell about the advantages and disadvantages of plastics in packaging material

Advantages: The use of plastic packaging can reduce packaging costs (low price), and its own weight is light, easy to form and good overall performance, and few materials can achieve such a variety of properties, which is its biggest advantage.

Disadvantages: Plastic products are difficult to degrade and have a great impact on the environment.

Besides, many plastic products are discarded after being used only once, causing a lot of waste.

4.3. Compare advantages and disadvantages of plastic bag and paper bag

Advantages Disadvantages

Plastic bag Water and oil proof Good stretch ability Relatively strong strength Low air permeability High transparency

Hard to degrade naturally Cause environmental pollution

Difficult to recycle

Paper bag More environmentally

friendly than plastic bags Naturally degradable Recyclable

Good printability

easy to break

The weight-bearing effect is not very good

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4.4. How can be planned packaging material so that increase the possibilities of recycling?

Take PET as an example, PET may produce toxic chemicals during first use, so it cannot go back into the original packaging application directly. Companies try to sandwich recycled PET between outer layer

‘barriers’ of virgin PET, but it not that successful. Biodegradable material can be used in the production of PS, so that increase the recyclability of PS. PP can be made biodegradable by controlled photo peroxidation. (Scott, 1999)

4.5. Compare between the use of plastics, mulch and glass in agriculture

Plastic mulching films decay slowly compare with traditional materials, so it can protect the roots of the plants very well. It also increases soil temperature and reduces water loss. However, the farmer must collect and dispose of the films after growing the crop. In greenhouses, glass is more expensive than plastics but can be used for a long time. Plastics break easily due to the weather, and glass is normally destroyed by accident. (Scott, 1999)

4.6. How additives effect on the possibilities of recycling?

PET does not need any additives, while PVC must be used some additives in order to it can be under the processing operation. PP also need additional additives in the recycling process to let it stable. (Scott, 1999)

4.7. How can be produced longer lifetime and safer polymer product?

Plastic products usually break because of bad designing, bad material, or their combination. The material can change during time for example due to exposure to heat or light. Polymers can be heat stabilized, light stabilized, or made fire retardant. Additives can be incorporated to thermoplastic polymers in an extruder where they are made into products.

Some additives and antioxidants are toxic. They might cause cancer if they are being exposed for a long period of time. To make sure new polymer additives are safe, animal tests can be done, but only epidemiological studies in humans are certain. (Scott, 1999)

4.8. How can we avoid polluting the environment by plastics waste in agriculture, transport, home, civil engineering etc?

Dumping the waste to a landfill should be the last resort. Collecting the plastics to be reprocessed to a new product is one possibility.

The plastic waste could also be utilized as fuel and replace traditional fossil fuels. The problem in burning the waste is that it often contains toxic heavy metal residues. Another way to re-use the waste material is to pyrolyze it.

Biodegradable polymers can be used in agriculture. When using normal plastic mulching films, the old films need to be removed before the next season. But when photo-biodegradable films are used, the films can be treated as biological waste and they do not interfere with automated harvesting. Photo- biodegradable polyethylene is a good alternative to be used in soil sterilization. The film is made so that it has been photo-biodegraded after the sterilization period.

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Degradable packaging for agriculture greatly reduces plastic litter on the fields. For example, baler twines made from photodegradable polypropylene. Baler twines are left on the ground after animals have eaten the hay inside. Photodegradable material biodegrades after one year. Protective bird netting that are needed only for one growing season can also be made from biodegradable polymers. (Scott, 1999)

References:

[1] Scott, G.1999. Polymers and the Environment. The Royal Society Chemistry.

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